The type of hybrid orbitals used by the chlorine atom in is:
— To determine the type of hybrid orbitals used by the chlorine atom in , we first need to find the steric number of the…
To determine the type of hybrid orbitals used by the chlorine atom in , we first need to find the steric number of the central atom (chlorine).
Step 1: Calculate the total number of valence electrons.
Chlorine (Cl) is in Group 17, so it has 7 valence electrons.
Oxygen (O) is in Group 16, so it has 6 valence electrons.
The ion has a -1 charge, meaning there is an additional electron.
Total valence electrons = electrons.
Step 2: Draw the Lewis structure.
Place Cl as the central atom. Connect the oxygen atoms to Cl with single bonds. This uses 4 electrons (2 bonds).
Remaining electrons = .
Distribute these 16 electrons as lone pairs to satisfy the octets of the oxygen atoms first. Each oxygen needs 6 more electrons (3 lone pairs). This uses electrons.
Remaining electrons = .
Place these 4 electrons as lone pairs on the central chlorine atom. This means Cl has 2 lone pairs.
Step 3: Determine the steric number.
Steric number = (Number of sigma bonds around the central atom) + (Number of lone pairs on the central atom).
In , there are 2 sigma bonds (Cl-O single bonds) and 2 lone pairs on the central Cl atom.
Steric number = .
Step 4: Determine the hybridization.
A steric number of 4 corresponds to hybridization.
Option Analysis:
- A) : This is correct. A steric number of 4 (2 bond pairs + 2 lone pairs) leads to hybridization. The molecular geometry is bent, but the electron geometry is tetrahedral.
- B) : This would correspond to a steric number of 3.
- C) : This would correspond to a steric number of 2.
- D) none of these: This is incorrect as is the correct hybridization.
Correct Answer: (A)