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ChemistryNEETClass 11Medium

The type of hybrid orbitals used by the chlorine atom in is:

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Quick Answer
Option A

To determine the type of hybrid orbitals used by the chlorine atom in , we first need to find the steric number of the…
Step-by-step solution
1

To determine the type of hybrid orbitals used by the chlorine atom in , we first need to find the steric number of the central atom (chlorine).

Step 1: Calculate the total number of valence electrons.
Chlorine (Cl) is in Group 17, so it has 7 valence electrons.
Oxygen (O) is in Group 16, so it has 6 valence electrons.
The ion has a -1 charge, meaning there is an additional electron.
Total valence electrons = electrons.

Step 2: Draw the Lewis structure.
Place Cl as the central atom. Connect the oxygen atoms to Cl with single bonds. This uses 4 electrons (2 bonds).
Remaining electrons = .
Distribute these 16 electrons as lone pairs to satisfy the octets of the oxygen atoms first. Each oxygen needs 6 more electrons (3 lone pairs). This uses electrons.
Remaining electrons = .
Place these 4 electrons as lone pairs on the central chlorine atom. This means Cl has 2 lone pairs.

Step 3: Determine the steric number.
Steric number = (Number of sigma bonds around the central atom) + (Number of lone pairs on the central atom).
In , there are 2 sigma bonds (Cl-O single bonds) and 2 lone pairs on the central Cl atom.
Steric number = .

Step 4: Determine the hybridization.
A steric number of 4 corresponds to hybridization.

Option Analysis:

  • A) : This is correct. A steric number of 4 (2 bond pairs + 2 lone pairs) leads to hybridization. The molecular geometry is bent, but the electron geometry is tetrahedral.
  • B) : This would correspond to a steric number of 3.
  • C) : This would correspond to a steric number of 2.
  • D) none of these: This is incorrect as is the correct hybridization.

Correct Answer: (A)

AnswerA·

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