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ChemistryJEE MainClass 11Medium

An ideal gas at constant temperature and pressure expands, then its:

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Quick Answer
Option A

Internal energy remains same

Concept: Internal energy of an ideal gas depends only on its temperature.
Step-by-step solution
1

Concept: Internal energy of an ideal gas depends only on its temperature.

Why (A) is correct:

For an ideal gas, the internal energy () is solely a function of its absolute temperature (). This is expressed as , where is the number of moles and is the molar heat capacity at constant volume. The problem states that the ideal gas expands at a constant temperature. Since the temperature remains constant, the internal energy of the ideal gas also remains constant.

Option Analysis:

  • A) Internal energy remains same: This is correct because for an ideal gas, internal energy is directly proportional to temperature, and the temperature is constant.
  • B) Internal energy decreases: This would imply a decrease in temperature, which contradicts the given condition.
  • C) Internal energy increases: This would imply an increase in temperature, which contradicts the given condition.
  • D) Entropy first increases and then decreases: When an ideal gas expands, its entropy always increases because the system becomes more disordered. There is no condition under which it would first increase and then decrease during a simple expansion at constant temperature and pressure.

Correct Answer: (A)

AnswerA·

Internal energy remains same

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