Select the correct order in agreement with the property indicated against it.
O2 > O22- (number of unpaired electrons)
— Let's analyze each option: Option A: H-F > H-Cl (Bond length) Bond length generally increases down a group as the…Let's analyze each option:
Option A: H-F > H-Cl (Bond length)
Bond length generally increases down a group as the atomic size increases. Chlorine is larger than fluorine, so the H-Cl bond length is greater than the H-F bond length. Therefore, H-F < H-Cl. This statement is incorrect.
Option B: He\u2082 > He\u2082\u207a (bond order)
Let's determine the bond order using Molecular Orbital Theory:
He\u2082: Total electrons = 4. Configuration: . Bond order = .
He\u2082\u207a: Total electrons = 3. Configuration: . Bond order = .
Since 0 < 0.5, He\u2082 < He\u2082\u207a in terms of bond order. This statement is incorrect.
Option C: O\u2082 > O\u2082\u00b2\u207b (number of unpaired electrons)
Let's determine the number of unpaired electrons using Molecular Orbital Theory:
O\u2082: Total electrons = 16. Configuration: . It has 2 unpaired electrons in the antibonding orbitals.
O\u2082\u00b2\u207b (Peroxide ion): Total electrons = 18. Configuration: . All electrons are paired. It has 0 unpaired electrons.
Since 2 > 0, O\u2082 has more unpaired electrons than O\u2082\u00b2\u207b. This statement is correct.
Option D: O\u2082 > O\u2082\u00b2\u207b (Bond length)
Let's determine the bond order first, as bond length is inversely proportional to bond order.
O\u2082: Bond order = .
O\u2082\u00b2\u207b: Bond order = .
Since the bond order of O\u2082 (2) is greater than O\u2082\u00b2\u207b (1), the bond length of O\u2082 will be shorter than O\u2082\u00b2\u207b. Therefore, O\u2082 < O\u2082\u00b2\u207b in terms of bond length. This statement is incorrect.
Correct Answer: (C)
O2 > O22- (number of unpaired electrons)