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ChemistryJEE MainClass 11Medium

Select the correct order in agreement with the property indicated against it.

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Quick Answer
Option C

O2 > O22- (number of unpaired electrons)

Let's analyze each option: Option A: H-F > H-Cl (Bond length) Bond length generally increases down a group as the…
Step-by-step solution
1

Let's analyze each option:

Option A: H-F > H-Cl (Bond length)

Bond length generally increases down a group as the atomic size increases. Chlorine is larger than fluorine, so the H-Cl bond length is greater than the H-F bond length. Therefore, H-F < H-Cl. This statement is incorrect.

Option B: He\u2082 > He\u2082\u207a (bond order)

Let's determine the bond order using Molecular Orbital Theory:

  • He\u2082: Total electrons = 4. Configuration: . Bond order = .

  • He\u2082\u207a: Total electrons = 3. Configuration: . Bond order = .

Since 0 < 0.5, He\u2082 < He\u2082\u207a in terms of bond order. This statement is incorrect.

Option C: O\u2082 > O\u2082\u00b2\u207b (number of unpaired electrons)

Let's determine the number of unpaired electrons using Molecular Orbital Theory:

  • O\u2082: Total electrons = 16. Configuration: . It has 2 unpaired electrons in the antibonding orbitals.

  • O\u2082\u00b2\u207b (Peroxide ion): Total electrons = 18. Configuration: . All electrons are paired. It has 0 unpaired electrons.

Since 2 > 0, O\u2082 has more unpaired electrons than O\u2082\u00b2\u207b. This statement is correct.

Option D: O\u2082 > O\u2082\u00b2\u207b (Bond length)

Let's determine the bond order first, as bond length is inversely proportional to bond order.

  • O\u2082: Bond order = .

  • O\u2082\u00b2\u207b: Bond order = .

Since the bond order of O\u2082 (2) is greater than O\u2082\u00b2\u207b (1), the bond length of O\u2082 will be shorter than O\u2082\u00b2\u207b. Therefore, O\u2082 < O\u2082\u00b2\u207b in terms of bond length. This statement is incorrect.

Correct Answer: (C)

AnswerC·

O2 > O22- (number of unpaired electrons)

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