Shape of is
see-saw
— To determine the shape of , we first need to find its hybridization and the number of lone pairs on the central sulfur…To determine the shape of , we first need to find its hybridization and the number of lone pairs on the central sulfur atom using VSEPR theory.
Step 1: Determine the total number of valence electrons.
Sulfur (S) is in Group 16, so it has 6 valence electrons.
Fluorine (F) is in Group 17, so it has 7 valence electrons.
Total valence electrons = electrons.
Step 2: Determine the number of bond pairs and lone pairs.
In , sulfur is the central atom. It forms 4 single bonds with 4 fluorine atoms.
Number of bond pairs = 4.
Electrons used in bonding = electrons.
Remaining electrons = electrons. These are distributed as lone pairs on fluorine atoms (3 lone pairs each, electrons) and on the central sulfur atom.
Electrons remaining for central atom = electrons.
Number of lone pairs on sulfur = lone pair.
Step 3: Determine the steric number and hybridization.
Steric number = Number of bond pairs + Number of lone pairs = .
A steric number of 5 corresponds to hybridization.
Step 4: Determine the electron geometry and molecular shape.
For a steric number of 5, the electron geometry is trigonal bipyramidal. With 4 bond pairs and 1 lone pair, the lone pair occupies an equatorial position to minimize repulsion. This arrangement results in a distorted tetrahedral shape, which is commonly known as a see-saw shape.
Option Analysis:
- A) tetrahedral: This shape occurs with 4 bond pairs and 0 lone pairs (e.g., ). has 1 lone pair.
- B) square planar: This shape occurs with 4 bond pairs and 2 lone pairs (e.g., ) or 4 bond pairs and 0 lone pairs in some transition metal complexes. has 1 lone pair.
- C) trigonal pyramid: This shape occurs with 3 bond pairs and 1 lone pair (e.g., ). has 4 bond pairs and 1 lone pair.
- D) see-saw: This is the correct shape for a molecule with 4 bond pairs and 1 lone pair, derived from a trigonal bipyramidal electron geometry.
Correct Answer: (D)
see-saw