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ChemistryJEE MainClass 11Medium

Select the incorrect statement.

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Quick Answer
Option B

σ-bond is weaker than a π-bond 

Let's analyze each statement: A) Double bond is shorter than a single bond: This statement is correct.
Step-by-step solution
1

Let's analyze each statement:

A) Double bond is shorter than a single bond: This statement is correct. A double bond involves the sharing of four electrons between two atoms, leading to a stronger attraction and a shorter bond length compared to a single bond (sharing of two electrons). For example, C-C bond length is ~1.54 Å, while C=C bond length is ~1.34 Å.

B) -bond is weaker than a -bond: This statement is incorrect. A -bond is formed by the head-on (axial) overlap of atomic orbitals, resulting in a strong bond. A -bond is formed by the sideways (lateral) overlap of p-orbitals, which is less effective and results in a weaker bond compared to a -bond. While a double bond (one and one bond) is stronger than a single bond (one bond), the individual component is weaker than the component.

C) Double bond is stronger than a single bond: This statement is correct. A double bond consists of one -bond and one -bond. A single bond consists of only one -bond. Since a double bond has more shared electrons and a -bond in addition to a -bond, it requires more energy to break than a single bond.

D) Covalent bond is stronger than a hydrogen bond: This statement is correct. Covalent bonds are intramolecular forces that involve the sharing of electrons and are typically much stronger (bond energies ranging from 150-1100 kJ/mol) than intermolecular forces like hydrogen bonds (bond energies typically 10-40 kJ/mol). Hydrogen bonds are electrostatic attractions between a hydrogen atom covalently bonded to a highly electronegative atom (like O, N, F) and another electronegative atom.

Therefore, the incorrect statement is B.

Correct Answer: (B)

AnswerB·

σ-bond is weaker than a π-bond 

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