Correct Lewis representation of O3 molecule is:
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Quick Answer
Option C — To determine the correct Lewis structure for O₃ (ozone), we need to follow the steps for drawing Lewis structures: Step…
Step-by-step solution
1AnswerC·
To determine the correct Lewis structure for O₃ (ozone), we need to follow the steps for drawing Lewis structures:
- Step 1: Calculate total valence electrons.
Each oxygen atom has 6 valence electrons. For O₃, total valence electrons = . - Step 2: Draw a skeletal structure.
The three oxygen atoms are connected in a bent arrangement. Let's label them O₁ - O₂ - O₃, where O₂ is the central atom. - Step 3: Place two electrons between each bonded atom.
O₁ - O₂ - O₃. This uses electrons. Remaining electrons = . - Step 4: Distribute remaining electrons as lone pairs to terminal atoms first to satisfy octets.
O₁ needs 6 more electrons (3 lone pairs) to complete its octet. O₃ needs 6 more electrons (3 lone pairs) to complete its octet. This uses electrons. Remaining electrons = . - Step 5: Place any remaining electrons on the central atom.
The 2 remaining electrons are placed on the central O₂ atom as one lone pair. - Step 6: Check octets and form multiple bonds if necessary.
At this point:- O₁ has 2 (bond) + 6 (lone pair) = 8 electrons (octet satisfied).
- O₂ has 2 (bond) + 2 (bond) + 2 (lone pair) = 6 electrons (octet NOT satisfied).
- O₃ has 2 (bond) + 6 (lone pair) = 8 electrons (octet satisfied).
- Step 7: Final Lewis Structure (Resonance).
This leads to two resonance structures for O₃:
Structure 1: O₁=O₂-O₃
O₁: 2 lone pairs, 1 double bond (8 electrons)
O₂: 1 lone pair, 1 double bond, 1 single bond (8 electrons)
O₃: 3 lone pairs, 1 single bond (8 electrons)
Structure 2: O₁-O₂=O₃
O₁: 3 lone pairs, 1 single bond (8 electrons)
O₂: 1 lone pair, 1 double bond, 1 single bond (8 electrons)
O₃: 2 lone pairs, 1 double bond (8 electrons)
Both resonance structures are valid. The actual structure is a resonance hybrid of these two.
Option Analysis:
- A) This structure shows a triple bond and a single bond. The central oxygen would have 10 electrons (octet violation). Also, the total valence electrons are incorrect.
- B) This structure shows two double bonds. The central oxygen would have 8 electrons, but the terminal oxygens would have 6 electrons each (octet violation).
- C) This option correctly depicts one of the resonance structures of O₃, with a double bond on one side and a single bond on the other, and all atoms satisfying the octet rule. The central oxygen has one lone pair. This matches our derived structure.
- D) This structure shows two single bonds and two lone pairs on the central oxygen, meaning the central oxygen has only 6 electrons (octet violation).
Correct Answer: (C)